It might be a bit of a cliché, but my pick would be Teenage Kicks by the Undertones. It’s such a perfect representation of its times, there’s a longing in the lyrics that I still feel every time I hear the song, and while not technically a masterpiece in terms of depth or skills, there’s nothing you could add or change that would make the song any better.
Or if a partial song counts, there’s of course that guitar solo by Prince around the 03:25 mark.
I live in Switzerland, where downloading copyrighted material for personal use is legal, so your situation may differ. If I don’t find what I’m looking for in a DRM-free store, on eMule and on the high seas, I just download it from YouTube. The quality is not the best but usually sufficient. Try the NewPipe app on Android (if applicable) or https://de.savefrom.net/ - be aware that the latter should only be visited with a good ad blocker and antivirus.